For trim just use a fine detail brush, dip it in the colour of choice, and make fine stokes of end of carapace.
If ya want it glossy, I think you can buy this special paint wich makes it all shiny. Altough you could use PVA glue since it dries transparent and shiny. I have never used gloss technique myself but I do use the trim effect, looks pretty cool on ma 'nids.
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